Interpreting Results and Making Informed Decisions in Groundwater Monitoring

The ability to accurately interpret the results of groundwater tests is essential for making informed decisions that protect our environment and public health. This article delves into the interpretation of common substances monitored in groundwater, including Volatile Organic Compounds (VOCs), Semi Volatile Organic Compounds (SVOCs), and Per- and Polyfluoroalkyl Substances (PFAS), and the decision-making processes driven by this data.

Understanding VOCs in Groundwater

Volatile Organic Compounds are common contaminants in groundwater. They include chemicals like benzene, toluene, ethylbenzene, and xylene (BTEX), often found in industrial solvents and petroleum products.

When interpreting VOC levels, it’s crucial to compare the concentrations against regulatory standards, such as those set by the Environmental Protection Agency (EPA). For example, the EPA’s maximum contaminant level (MCL) for benzene in drinking water is 5 parts per billion (ppb). Levels exceeding this threshold indicate a potential health risk and necessitate remedial action.

The Impact of SVOCs

Semi Volatile Organic Compounds, though less volatile than VOCs, are equally concerning. These include compounds like naphthalene and phenols, commonly originating from industrial discharges and pesticide runoff.

SVOCs tend to adhere to soil particles, making their migration slower but persistent. Interpreting SVOC data involves assessing both concentration levels and the extent of spread. Remediation strategies might involve soil excavation or in-situ treatment methods.

PFAS: The Emerging Contaminant

PFAS, often referred to as “forever chemicals,” are a group of man-made compounds used in various industrial applications and consumer products. Due to their persistence and bioaccumulation potential, PFAS are particularly concerning.

Interpreting PFAS levels involves understanding both individual compound concentrations and total PFAS burden. With evolving regulations, and new groups of PFAS constantly being discovered and researched, it’s important to stay updated on guideline values. The EPA finalized MCL’s for PFAS in drinking water in April of 2024, with levels for PFOA and PFOS set at 4 parts per trillion (ppt). Other PFAS, such as PFNA, PFHxS and “GenX Chemicals” are set at 10 ppt.

Data-Driven Decision Making

The interpretation of groundwater contaminants drives critical decisions in environmental management. For most contaminants, exceeding regulatory thresholds often triggers site investigations to determine the contamination source and extent. Remediation decisions are based on factors like contaminant type, concentration, and site characteristics.

Now that PFAS standards are set, facilities such as wastewater treatment plants and landfills must comply with the new limits over the next few years. As these facilities are investigated, sites where PFAS levels are over the limits will require long term monitoring, upstream investigations, and extensive remediation plans until the sites are below the thresholds. Throughout this investigative process, the industry is working hard to develop cost effective remediation plans for these “forever chemicals”.

Conclusion

Interpreting groundwater monitoring data is a nuanced and critical process. Understanding the implications of various contaminants like VOCs, SVOCs, and PFAS is key to making informed decisions for environmental and public health protection.

Utilizing passive groundwater sampling methods in your groundwater monitoring can ensure accurate and timely data, allowing you to make decisions quicker and move faster to act. The low cost of passive sampling can also free up more funds to allocate towards remediation and compliance.

Schedule a free consultation to learn more about how passive groundwater sampling equipment from EON can help you make better decisions while saving time and money.

The Importance of Proper Data Analysis in Groundwater Monitoring

Groundwater monitoring is a critical aspect of environmental assessment, resource management, and contamination cleanup efforts. Accurate data analysis not only informs stakeholders of current conditions but also guides remediation and protection strategies. This article delves into the best practices and challenges in analyzing data from groundwater samples, with a focus on the treatment of passive samples.

Best Practices in Data Analysis

Groundwater monitoring data offers a snapshot of the subsurface environment’s health. Best practices in data analysis involve:

  • Temporal Consistency: Regular sampling provides a timeline of data that can reveal trends.
  • Spatial Accuracy: Precise location mapping ensures data relevance to specific contamination sites or aquifers.
  • Analytical Precision: Utilizing accredited laboratories and validated methods for analysis guarantees the reliability of data.

However, challenges abound. Data variability due to seasonal changes, cross-contamination risks during sampling, and the complexity of subsurface geology can skew results. Addressing these requires a methodical approach to sampling and analysis.

Groundwater monitoring projects encounter a variety of contaminants ranging from volatile organic compounds (VOCs) to heavy metals and emerging contaminants like PFAS and 1,4 Dioxane. Each type of contaminant presents unique challenges and considerations in data analysis, often requiring specialized approaches to ensure accurate assessment and interpretation.

Volatile Organic Compounds (VOCs)

Challenges:

  • Sample Preservation: VOCs are prone to evaporation and degradation. Therefore, maintaining the integrity of the sample from the field to the laboratory is crucial.
  • Detection Limits: Many VOCs are harmful at very low concentrations, necessitating highly sensitive analytical methods.

Considerations:

  • Method 8260: This is a standard EPA method for analyzing VOCs using gas chromatography/mass spectrometry (GC/MS).
  • Low-Flow Sampling Techniques: These can be used alongside passive sampling to reduce disturbance of the sample and prevent loss of VOCs.

Heavy Metals

Challenges:

  • Particulate Association: Metals can be present in dissolved form or bound to particles, and distinguishing between these forms is essential for accurate risk assessment.
  • Oxidation States: The toxicity and mobility of metals can vary significantly with their oxidation state, which can change during sampling and storage.

Considerations:

  • Sequential Extraction Procedures: These are used to differentiate between the speciated forms of metals.
  • Acidification: Adding acid to samples can preserve metals in their dissolved state for analysis.

PFAS

Challenges:

  • Diverse Chemical Properties: These contaminants have a wide range of chemical properties and behaviors in the environment, making standardized analysis difficult.
  • Difficulty to Destroy: PFAS are widely known as “forever chemicals” due to their lack of degradation and difficulty to destroy. Reliable and cost effective remediation methods are currently non-existent and are a focus for many environmental companies today.
  • Unknown Health Impacts: The health impacts of many emerging contaminants at trace levels are not well understood, complicating risk assessment.

Considerations:

  • Advanced Analytical Techniques: Techniques such as liquid chromatography-tandem mass spectrometry (LC-MS/MS) are often required for these contaminants.
  • Low Cost Investigation: Due to the low MCLs announced by the EPA for PFAS in drinking water, it is important that companies find technologies and adopt practices that decrease the cost of determining if PFAS is present. This will allow the allocation of more funds toward site remediation and cleanup.

Nutrients (Nitrogen, Phosphorus)

Challenges:

  • Biological Activity: Nutrients are subject to biological uptake and transformation, which can rapidly change concentrations.
  • Eutrophication Risk: Elevated levels can lead to eutrophication, and pinpointing sources is essential for mitigation.

Considerations:

  • In Situ Sensors: These can provide real-time monitoring of nutrient levels.
  • Isotopic Analysis: Nitrogen and phosphorus isotopes can help trace nutrient sources and pathways.

Organic Matter

Challenges:

  • Complex Mixtures: Natural organic matter consists of complex mixtures of thousands of different chemicals, complicating analysis.
  • Interference with Contaminant Measurements: Organic matter can bind with contaminants, affecting their detection and interpretation.

Considerations:

  • Total Organic Carbon (TOC) Analysis: This provides a measure of the organic content in a sample and can be a proxy for organic matter.
  • UV-Visible Spectroscopy: This can help characterize organic matter and understand its interactions with contaminants.

Proper data analysis begins with your sampling method and choosing the method that best suits the contaminates you are dealing with.

Passive Sampling: Revolutionizing Groundwater Data Collection

Passive groundwater sampling is an innovative method that offers several advantages over traditional techniques like pump-and-purge or low-flow sampling. This method uses a no-purge approach, allowing for the collection of samples without the need to remove large volumes of water. This reduces sample turbidity and avoids the disruption of the natural chemical conditions of the groundwater.

Benefits of Passive Sampling:

  • Cost-Effectiveness: Reduces time in the field and the volume of water needing disposal or safe storage.
  • Data Integrity: Minimizes disturbance to the water column, leading to representative samples that do not bias the sample.
  • Enhanced Safety: Lowers the risk of exposure to contaminants for field technicians.

Data Interpretation: Navigating the Complexities

Proper interpretation of groundwater data from passive sampling is paramount. It involves understanding the geochemistry of the site, the behavior of contaminants, and the potential for biodegradation or natural attenuation. Analysts must consider:

  • Contaminant Distribution: Recognizing the heterogeneous distribution of contaminants can affect sampling strategies.
  • Geochemical Indicators: Parameters such as pH, redox potential, turbidity, and conductivity can provide insights into subsurface conditions.
  • Time-Series Analysis: Evaluating changes over time can help distinguish between transient spikes and stable contamination levels.

Advancing Groundwater Monitoring with Passive Sampling

By offering an accurate representation of in-situ conditions, passive sampling can equip you with the data necessary to make informed decisions about remediation efforts and groundwater management.

The analysis of groundwater data, particularly from passive samples, is a cornerstone of effective environmental stewardship. Adhering to best practices in sampling and analysis, and overcoming the inherent challenges, ensures the protection of this vital resource for future generations.

Selecting the Right Type of Passive Groundwater Sampling Equipment

In environmental monitoring, selecting the best sampling equipment is crucial to your project’s success. If you are considering improving the sampling efficiency of your monitoring program with passive samplers, it is important to ensure the type of sampler you choose aligns with the needs of your project and the preferences of your team in the field.

Passive groundwater sampling, known for its balance of cost-effectiveness and reliability, presents a range of equipment choices suited to different projects, goals, and preferences in the field. Here, we dive into making that crucial choice, ensuring it’s not just about avoiding problems but setting the course for success.

Understanding Passive Groundwater Sampling

Passive groundwater sampling is a technique that collects groundwater samples without the need for purging prior to sampling. A passive sampler captures a representative sample within a specific interval of the monitoring well screen, avoiding the aerated or stagnant water at the top of the screen or in the casing. This method utilizes the natural flow of groundwater from the surrounding aquifer to refresh the monitoring well, allowing for an accurate representation of conditions.

Passive Diffusive Samplers (Single Membrane)

Functionality: Passive Diffusion Samplers collect a water sample containing contaminant molecules that have diffused through the pores of a semipermeable membrane filled with deionized water. Single membrane samplers are made from one, solid membrane and are used to sample for volatile organic compounds (VOCs).

Strengths: Their simple design makes them cost-effective and easy to deploy. They are particularly efficient for monitoring VOCs, offering high accuracy. Diffusion samplers offer a time weighted average of the last few days of groundwater flow, allowing for a more wholistic view of the aquifer’s characteristics.

Ideal Use Case: These samplers are best suited for long-term monitoring of VOCs in environments with stable groundwater conditions, where their precision and simplicity are most advantageous.

Dual Membrane Passive Diffusion Samplers

Functionality: Dual Membrane Passive Diffusion Samplers (sometimes called DMPDB’s) operate like standard diffusion samplers, but they are equipped with two semi-permeable membranes of different porosity, allowing for diffusion of different types of compounds.

Strengths: DMPDB’s offer a similar, time weighted average of the groundwater that provides a broader characterization of the aquifer. Due to their multiple membranes, they are especially effective for detecting a wide range of contaminants, including semi-volatile organic compounds (SVOCs), Metals and PFAS.

Ideal Use Case: These samplers are ideal for complex environmental sites with a diverse range of contaminants, where enhanced detection capabilities are required.

HydraSleeve No-Purge Samplers

Functionality: HydraSleeve No-Purge Samplers are designed for the efficient collection of discrete water column samples without the need for purging, optimizing the sampling process.

Strengths: Since HydraSleeves capture anything that is in the water within the sampling interval, they can be used to sample any contaminant found in groundwater. HydraSleeves are also the best passive sampler to maximize sample volume within a monitoring well.

Ideal Use Case: These samplers are particularly suitable on projects where the benefits of passive sampling are desired, but the sampling objectives require a snapshot in time, similar to a pumped or bailed sample. HydraSleeves are also the best passive sampler to use when 1 liter or more of volume is required per sample.

Comparing the Three Types of Passive Samplers: A Decision-Making Guide

When choosing between these types of passive samplers, several factors come into play:

Contaminant Profile: Understanding the types of contaminants present is crucial. For VOCs, traditional passive diffusion samplers are effective, while Dual Membrane samplers and HydraSleeves are necessary if you are sampling for more than VOC’s.

Volume Requirements: Consider the contaminants of concern and the volume your lab requires for each sample. If more than 1 liter is required per sample, HydraSleeves are generally recommended.

Project Team Preference: At most sites, the HydraSleeve™ or one of EON’s diffusion samplers will be able to align with your monitoring objectives. In these cases where more than one type of sampler is effective, it can come down to the team’s preference in equipment. Is the field team more familiar with one type of sampler?

EON Products: Catering to Diverse Monitoring Needs

At EON Products, we understand the diversity of groundwater monitoring projects and offer a range of passive groundwater sampling equipment to meet these varied needs.

Customized Solutions: We assist in selecting the most suitable sampler based on your project’s specific requirements.

Quality Assurance: Our products are designed to ensure accurate and reliable sampling results.

Expert Support: Our team provides ongoing support and advice, ensuring successful deployment and sampling.

Conclusion

Choosing the right type of passive groundwater sampling equipment is a critical step in ensuring the success of your monitoring projects. By understanding the distinct features and benefits of the different types of passive diffusive samplers and HydraSleeve No-Purge Samplers, you can make an informed decision.

Book a free consultation to learn more about this equipment and how it can help you on your next project.

Frequently Asked Questions

Q1: What are the environmental impacts of using passive samplers compared to traditional sampling methods?

The environmental impacts of using passive samplers compared to traditional sampling methods are quite notable. Passive samplers, by design, reduce the disturbance to the groundwater environment, minimizing the risk of cross-contamination and preserving the integrity of the site. This contrasts with traditional methods like pump-and-purge, which can disturb the natural state of the groundwater and generate significant volumes of wastewater. Additionally, passive samplers are often more energy-efficient and require less field time and resources, leading to a smaller environmental footprint. These advantages make passive samplers a more environmentally sensitive choice for groundwater monitoring.

What Types of Sites is Passive Sampling Good For?

Passive groundwater sampling is an increasingly popular sampling method. Many firms are adopting passive sampling over traditional methods because of the huge time and cost savings it provides. But how do you know what sites are best suited for passive groundwater sampling techniques? 

This article will outline which sites are best suited for passive groundwater sampling, providing insights into why this method delivers exceptional results, and how to determine its suitability for your project.

For more insights check out The Ultimate Guide to Passive Groundwater Sampling

When to Choose Passive Groundwater Sampling

1. Industrial and Commercial Sites

Sites with industrial legacies, like manufacturing plants, chemical storage, and processing facilities, can benefit from the cost savings and minimal site disturbance passive sampling offers. Whether the site is a part of “upstream” contamination source assessments, or it is in active remediation, the cost savings from passive sampling will be a benefit to clients at industrial and commercial sites.

2. Department of Defense (DoD) Sites

Military sites often deal with a range of contaminants, from jet fuels to chlorinated solvents, and more recently PFAS. The large monitoring well networks and scope of work at these military sites makes passive sampling a perfect solution. Many firms and DoD sites have cut their sampling time and costs in half by switching to passive sampling.

3. Solid Waste Sites

Solid waste sites, such as landfills in detection monitoring, are prime candidates for passive sampling. Due to the recurring nature of these sampling events, adding passive samplers to the monitoring program can reduce time on site when volume requirements aren’t too high. A combination of traditional sampling methods and passive methods may be the most efficient way to monitor landfills that have some wells in assessment that require more volume, but still have other wells that can be sampled passively.

4. Mining Sites

Mining operations can result in complex contaminant profiles in groundwater. Passive sampling can be particularly effective due to its ability to operate in remote locations and under harsh conditions where traditional methods might be logistically challenging. A unique passive sampling approach using HydraSleeves connected to drones has also been applied to sample surface water at pit lakes to increase safety at these locations.

5. Other Contaminated Sites

In general, any site with groundwater contamination issues, such as brownfields or other state or federally monitored sites, may be a good fit for passive sampling, especially where long term monitoring programs are established.

Why Passive Sampling Triumphs on These Sites

The advantages of passive sampling are numerous, but they particularly shine on the aforementioned sites due to several key factors:

  • Cost Efficiency: Passive sampling is less labor-intensive and can reduce costs related to equipment, personnel, and disposal of purged water.
  • Reduced Disturbance: Unlike traditional methods, passive sampling does not require extensive water withdrawal, which can disturb the site’s equilibrium.
  • Ease of Deployment: Devices used for passive sampling can be easily deployed and left in situ for extended periods, allowing for reduced mobilizations and time on site.
  • Improved Safety: With less equipment and reduced handling of contaminated water, passive sampling enhances safety for field technicians.

Assessing Site Suitability: A Checklist

To determine whether a site is suited for passive groundwater sampling, consider the following:

  • Contaminant Type and Sampler Selection: Have you chosen a passive sampler that can sample for your contaminants of concern?
  • Hydrogeology: Does the site’s hydrogeology support passive sampling devices? Consider the aquifer’s permeability and the presence of distinct water-bearing zones.
  • Accessibility: Can the sampling locations be easily accessed for the deployment and retrieval of passive devices?
  • Regulatory Acceptance: Have you discussed using passive samplers on this site with your regulators?
  • Project Goals: Are the project’s data quality objectives aligned with the data that passive sampling can provide?

If the answer to most of these questions is yes, passive groundwater sampling could be an excellent choice for your project.

The Path Forward

Choosing the right groundwater sampling method is crucial for the success of any monitoring or remediation project. Passive groundwater sampling is not a one-size-fits-all solution, but for many sites, it offers significant improvements over traditional methods in terms of efficiency, cost, safety, and data quality.

Book a free consultation to learn more about passive sampling and its potential benefits for your projects.

Frequently Asked Questions

Q1: How does the data quality of samples from passive groundwater sampling compare to those obtained from traditional methods in terms of long-term monitoring?

The data quality of passive groundwater sampling is equivalent to that of traditional methods for long-term monitoring. Through dozens of third-party studies, passive sampling has been established as a valid, representative way to sample groundwater. Passive sampling’s consistency is particularly advantageous for long-term monitoring where understanding trends over time is crucial.

Q2: What are the limitations of passive groundwater sampling, and how can they be addressed to ensure the most effective use of this method?

Passive groundwater sampling’s limitation is that it can sample a finite amount of volume at one time, dependent upon the specific monitoring well. Sites sampling for multiple contaminant types per well may require larger volume samples than passive samplers can deliver. However, certain passive samplers can hold up to 2L of water in one sampler, and multiple samplers can be stacked in the well to obtain higher volumes. Therefore, passive sampling is still a viable solution for most projects.

Q3: Can passive groundwater sampling be integrated into existing groundwater monitoring programs that currently use traditional methods, and what would be the steps for a successful integration?

Passive groundwater sampling can be integrated into existing monitoring programs by working with your regulator on an implementation strategy. In many cases, this integration starts with a pilot study that compares the passive sampler results with data obtained from traditional methods. If passive sampling proves effective and is approved, it can be adopted site wide if applicable. Training for field personnel on proper deployment and retrieval techniques, along with understanding the data’s interpretation, is also critical. Finally, updating the monitoring program’s standard operating procedures to include passive sampling will ensure consistency and compliance across the board.

Understanding Passive Diffusion Bags (PDBs)

More than 20 years ago Passive Diffusion Bags (PDBs) were introduced as a more streamlined, cost-effective solution for sampling for Volatile Organic Compound (VOC) concentrations in groundwater monitoring wells. Passive diffusion samplers have become widely used in the years since their introduction, leading to the development and use of samplers using membranes with different pore sizes that can accurately sample for all contaminants, including, metals, inorganics, ionic compounds, SVOCs and emerging contaminants such as 1,4 Dioxane and PFAS.

PDBs are typically 18 to 28-inch-long flexible, tubular “bags”, made from, semi-permeable, polyethylene membranes. They are filled with deionized water, sealed, and deployed on a weighted tether into the saturated screen interval of 1-inch and larger monitoring wells.

The key principle behind PDBs is that contaminant molecules dissolved in water will naturally diffuse or “flow” from areas of higher concentration to lower concentration if there is a pathway through which the molecules can move. When PDBs are deployed, contaminants in the groundwater diffuse through the microscopic pores in the membrane and equilibrate with the deionized water inside the bag over about 2-3 weeks’ time.

Once equilibrium is reached, the concentrations in the PDB continually adjusts to the surrounding groundwater concentrations so that the sampler always represents the constituents of the last several days of residence time.

That means PDBs can be installed at one sampling event and left in-place, indefinitely, until the next sampling event and then recovered with a representative sample. No bailing, no pumping, no waiting for parameters to stabilize. Simply pull out the sampler and discharge into a sample container.

Ideal Applications of PDBs

PDBs are particularly well-suited for specific types of environmental sites:

Contaminated Sites: Ideal for monitoring pollutants, PDBs can provide accurate readings of contaminant levels over time, essential to assist in tracking contaminant migration and remediation efforts.

Risk Assessment Sites: PDBs can be deployed to evaluate whether there is groundwater contamination flowing through a site’s underground aquifer. PDBs are with wide-ranging contaminant capability are selected for application at solid waste locations, UST sites and monitoring networks across all industries.

Large Sites with Many Wells: Substantial cost-savings roll-up as more wells convert to passive sampling and reduce the time/labor demand.

Remote and High-Traffic Sites: Because Passive Diffusion Samplers are small, lightweight, and don’t need cumbersome support equipment, it’s easier to get to remote sites and in-and-out of high traffic areas in minutes, adding a safety component to passive sampling.

Slow-Recharge Wells:  No waiting for wells to recover from being pumped down and no concern about aerated samples in re-charging wells that have been pumped. Simply install at one event and recover at the next.

Benefits of Using PDBs

Time Efficiency: PDBs significantly reduce the time required for sample collection and processing. They can be left in situ for extended periods and maintain a dynamic equilibrium with the surrounding aquifer, allowing for accurate, representative data from the period when sample collection occurs.

Cost-Effectiveness: With fewer resources needed for sample collection and processing, PDBs offer a more economical solution compared to traditional groundwater sampling methods.

Ease of Use: PDBs are straightforward and easy to deploy and retrieve, making them accessible even for teams with limited experience in passive sampling methods.

Reduced Risk of Contamination: The closed system of PDBs minimizes the risk of sample contamination, ensuring reliable results.

Environmental Friendliness: PDBs are a more sustainable option, generating less waste and requiring fewer consumables than traditional methods.

Best Practices for Using PDBs

To maximize the effectiveness of PDBs in your groundwater sampling projects, consider the following best practices:

Sampler Selection: PDBs can be made with membranes of different porosity, allowing for accurate sampling of different types of compounds. Ensure the sampler you choose for your project aligns with your site’s contaminants of concern.

Proper Deployment: Ensure that PDBs are correctly placed in the monitoring wells and at the right depths to sample the targeted contaminants.

Deploy After Retrieval: Eliminate duplicate mobilizations at long term monitoring sites with multiple sampling events, by deploying your next event’s samplers into your wells after you’ve retrieved your prior event’s PDBs. The PDBs can stay in the wells uncompromised and will be ready for quick retrieval at your next event. 

Conclusion

Passive Diffusion Bags are a proven technology in groundwater sampling. Their ability to provide accurate, cost-effective, and efficient sampling makes them an invaluable tool for environmental consultants.

As the industry continues to evolve, embracing innovative technologies like PDBs will be crucial in staying ahead and delivering superior environmental monitoring services.

For more information read The Ultimate Guide to Passive Groundwater Sampling.

Q1: How can the deployment of PDBs be optimized for different types of environmental sites (e.g., urban vs. rural, shallow vs. deep groundwater)?

The deployment of Passive Diffusion Bags (PDBs) can be optimized for various environmental sites by considering specific site characteristics. In urban areas, where space and access might be limited, PDBs are advantageous due to their minimal setup requirements. They can be easily deployed in monitoring wells situated in confined spaces, which is often a challenge in densely built-up areas. For rural sites, PDBs are beneficial in reducing the frequency of site visits, which can be logistically challenging and costly due to remote locations.

When considering groundwater depth, PDBs are versatile. For shallow groundwater monitoring, they provide an efficient way to sample without extensive pumping, which can disturb the water table and produce large volumes of contaminated wastewater. In deeper wells, PDBs should be accurately placed at specific depths to target the contaminants of interest, considering factors like groundwater flow and contaminant concentration gradients. This targeted deployment is crucial in mining sites or areas with stratified contaminant layers.

In both urban and rural settings, it’s essential to understand the hydrogeology of the site. Knowledge of the groundwater flow, contaminant types, concentration variations, and sample volume requirements, can guide the optimal type and placement of PDBs in the wells.

Q2: What are some potential limitations or challenges of using PDBs in groundwater sampling, and how can they be addressed?

While PDBs offer several advantages for groundwater sampling, there are limitations and challenges to consider. One of the main limitations is the amount of volume that can be sampled at one sampling event. With any passive sampler, including PDBs, you are limited to sample the water that is within the fully saturated length of the well screen. PDBs can be built to sample up to 1-L per sampler, and multiple PDBs can be deployed on a single tether to obtain more sample volume. Users should understand that there are cases where saturated screens are too short to provide adequate sample volume for some laboratory methods.

Another challenge is the potential for biofouling or sediment buildup on the bags, especially in wells with high microbial activity or sedimentation. This can affect the accuracy of the samples. Regular maintenance and monitoring of the PDBs can help identify and mitigate these issues.

Q3: Can the data collected from PDBs be integrated with other environmental monitoring technologies to provide a more comprehensive understanding of a site’s condition?

Integrating data collected from PDBs with other environmental monitoring technologies can provide a more comprehensive understanding of a site’s condition.

Geospatial technologies, such as Geographic Information Systems (GIS), can be used to map and analyze the spatial distribution of contaminants. Combining PDB data with GIS allows for the visualization of contaminant plumes and identification of trends over time.

Additionally, integrating PDB data with real-time monitoring systems, like automated water quality sensors, can provide a more dynamic picture of groundwater conditions. These sensors can continuously monitor parameters like pH, temperature, and conductivity, offering immediate insights into changes in the groundwater environment. By combining PDB data with other monitoring tools, environmental consultants can gain a more holistic view of the site’s condition, enabling more informed decision-making for remediation and management strategies. This integrated approach can be key to effective environmental monitoring and management.

Revolutionizing Groundwater Monitoring: The Advantages of Passive Grab Samplers

Whether you are assessing a site to understand potential contamination, watching for long-term changes, or evaluating the effectiveness of remediation efforts at known contaminated sites, groundwater monitoring is a critical aspect of environmental management.

Bailing and pumping are active sampling methods that have been the de-facto methods for acquiring groundwater samples. Innovations over the past 25 years, particularly the use of Passive Grab Samplers, have transformed the way environmental consultants can approach sampling tasks. This article delves into the mechanics of Passive Grab Samplers where they can be used and highlights the benefits they offer over active groundwater sampling methods.

Understanding Passive Grab Samplers

How They Work:

Passive Grab Samplers are simple and efficient. The process relies on natural groundwater flow to bring aquifer-quality water through the screen, where the passive sampler “grabs” the water from an interval without changing the velocity or direction of natural flow. The water and everything in it is sealed inside the device, isolating it from overlying water layers as the sampler is removed from the well.

Unlike active methods, passive sampling collects a groundwater sample without pulling stagnant or aerated water in from the casing or other intervals. The stagnant and other non-representative water is by-passed and therefore no purging and time-consuming monitoring of stabilization parameters is needed to obtain a representative sample.

HydraSleeves – A Leading Example:

The HydraSleeve is a passive grab sampler that makes groundwater sampling a simple, three-step operation that is more efficient than traditional purge methods involving pumps or bailers.

The HydraSleeve is a collapsible, flexible tube of low- or high-density polyethylene (LDPE or HDPE) that is sealed at the bottom end and has a self-sealing reed valve at the open top end. The HydraSleeve sampler is installed into the water column within the screen interval of the well, causing very little displacement or disturbance. Hydrostatic pressure keeps the device closed until it is pulled upward through the water during retrieval. As the sampler is pulled upward, to collect the sample, the tube opens and sleeves around the stationary water to collect a “core” of the water in the interval.  When the sampler is full the valve closes and seals, ensuring that only the specific target interval is sampled. 

HydraSleeve works using a 3-step process:

  1. Lower the empty HydraSleeve into the target interval of the well screen on a simple, reusable suspension tether. You may stack multiple sleeves on the suspension tether for vertical profiling or additional volume.
  2. Once the well has re-stabilized from the slight disturbance of adding the sampler to the well, pull the HydraSleeve upward through the sample interval. This allows the check valve to open and the sample to be collected. When the sampler has passed through the sample zone and is full, the check valve will automatically close.
  3. Retrieve the full HydraSleeve from the well, discharge into the appropriate lab bottles, and send to the lab per standard procedures.

Suitability for Different Sites

Optimal Site Conditions:

Passive Grab Samplers excel in most groundwater environments but are particularly advantageous at long term monitoring sites with multiple sampling events because they can acquire samples at a fraction of the cost of pumping or bailing. Passive Grab Samplers are also a good solution for sites with slow recharge, diverse contaminant profiles, unknown contaminants, contaminants of emerging concern (PFAS, 1,4 Dioxane) or those requiring depth-specific sampling. They are ideal for monitoring contaminated sites, solid waste disposal areas, and mining sites, where accurate and comprehensive water quality data is crucial.

Benefits Over Traditional Methods

Time and Cost Efficiency:

One of the most significant advantages of Passive Grab Samplers is their time and cost efficiency. Traditional methods, often labor-intensive and time-consuming, can escalate project costs. Passive Grab Samplers can collect samples in less than 10 minutes and cut total field time by more than half.

Sample Integrity and Reliability:

Passive Grab Samplers offer enhanced sample integrity. They reduce the risk of cross-contamination and disturbance to the water’s chemistry, ensuring an accurate representation of in-situ conditions.

Ease of Use and Safety:

Passive Grab Samplers like HydraSleeves require minimal training and no special tools. They are also small, easy to transport, and require no set up time prior to sample collection. This means less exposure for field personnel at high-traffic areas and less gear to lug to remote sites.

Environmental Impact:

From an environmental standpoint, Passive Grab Samplers are less intrusive. They minimize disturbance to the aquifer and require no power source to function. Because no purge-water is generated, storage, transportation, and disposal of hazardous or contaminated IDW is eliminated. The small materials footprint aligns with the increasing emphasis on sustainable and eco-friendly practices in environmental monitoring.

Conclusion

The shift towards Passive Grab Samplers like HydraSleeve represents a significant advancement in groundwater monitoring. Their ease of use, cost-effectiveness, and ability to provide reliable and accurate data make them an excellent choice for environmental consultants. As the field of environmental monitoring continues to evolve, embracing these innovative tools will be key to efficient, effective, and responsible groundwater management.

How To Implement Passive Sampling into Your Existing Groundwater Monitoring Program

Many active groundwater monitoring programs could benefit from implementing passive sampling methods on their site. But what is the best way to implement passive sampling into your existing program?

While the idea of changing sampling methods mid-project may initially seem like a burden, the effort pays off quickly for the consultants and stakeholders who make this transition. In many cases, the transition pays for itself in the first year, providing benefits for the remaining project life-cycle.

Adding or changing to passive samplers will make the sampling events much easier, will reduce the amount of time it takes to sample, and will eliminate storage and compliance costs of handling IDW. These benefits can result in recurring cost reductions to your sampling programs of 50-70%.

This blog post will explore how you can effectively integrate passive sampling into your active groundwater monitoring programs for optimal results.

Understanding Passive Groundwater Sampling

Before diving into integration strategies, it’s important to understand passive groundwater sampling. Passive groundwater sampling is a technique that collects groundwater samples without the need for purging prior to sampling.

A passive sampler captures a representative sample within a specific interval of the monitoring well screen, avoiding the aerated or stagnant water at the top of the screen or in the casing. This method utilizes the natural flow of groundwater from the surrounding aquifer to refresh the water in the screen, allowing for an accurate representation of conditions.

Integrating Passive Sampling into Your Monitoring Program

The integration of passive sampling into an existing program requires careful planning. Begin by assessing the objectives of your monitoring program. Consider factors like the contaminants of concern, the size of the well and location of saturated screen intervals, and sample volume requirements. Identify sites where passive sampling can yield the most benefit, especially long-term monitoring projects, sites with sampling events that take the most amount of time, or sites with contaminants like PFAS that require special field sampling efforts.

Once you have identified the sites where passive sampling can provide the most benefit, it is time to get your local regulatory agency involved. Many regulators are familiar passive sampling and may not require much additional information to approve the changes to your monitoring plan.

In some circumstances, regulators may request side-by-side evaluations between passive samplers and the legacy method of sampling at that site. These evaluations are straightforward and generally low cost, with a few representative wells used to compare results from passive samplers to historical or real-time results from the method being replaced.

EON Products has helped many customers plan and implement successful side-by-side evaluations prior to adding passive sampling to their monitoring programs.

Can Passive and Traditional Sampling Coexist in a Single Project?

Yes, many sites can use more than one sampling method across their monitoring well network, depending on the hydrogeological conditions and goals of the project.

For example, a site may adopt passive sampling on most of their wells as a strategy to reduce time on site and decrease cost. However, there may be a few wells that are sampled for more contaminants of concern that may require more volume than a passive sampler can provide. In this scenario, a combination of passive samplers at some wells and pumps at others could be the most effective and efficient way to manage the project. This is a common setup in landfills with wells in various stages of regulatory compliance.

Transition and Training

Transitioning to an approach that includes passive sampling involves training and adaptation. Ensure your team is well-versed in both passive and traditional sampling techniques. This dual expertise allows for flexibility and adaptability in various project scenarios.

The good news is that passive sampling methods require little training or special equipment and are much easier to install and use than low-flow pumps.

EON Products provides field-practical, Standard Operating Procedures and training videos for each passive sampling technique and side-by-side evaluation. Our staff are always ready to assist in setting up your program, using experience gained from hundreds of successful passive sampling installations. 

Meeting Site Objectives

Before introducing a new sampling method, it is helpful to list the project objectives and decision criteria. That helps ensure that you compare results from the old and new methods through a lens that aligns with your monitoring program’s goals.

  • Is this a site assessment that requires sampling for a large list of contaminants at low lab reporting limits?
  • Is it a long-term monitoring project with the focus on whether Maximum Reporting Limits (MCLs) are exceeded?
  • Is this an active remediation site looking at the remediation efficiency? 
  • Perhaps a site working toward eventual closure and contaminant concentration trends?
  • Are there contaminants requiring special sampling efforts?

Highlighting the project sampling objectives up-front helps determine what is important when comparing results from different sampling methods, so that practical sampling method decisions can be made.

Best Practices for Implementing Passive Sampling

Site Selection: Use site-specific information to decide where passive sampling can be most effective.

Consult with your Regulator: Work with your Regulator to understand what requirements are needed, if any, for approval of passive sampling on your site.

Evaluation Study Planning: If a side-by-side method evaluation is required, work with EON to ensure the SOP for the evaluation meets all requirements. Determine the right correlation method that aligns with your project’s monitoring plan.

What to Keep in Mind When Using Both Methods

Cost-Benefit Analysis: Evaluate the cost savings from reduced labor and equipment needs against the initial investment required to make changes to your monitoring plan, then compare the project life-cycle costs.

Regulatory Compliance: Ensure that passive sampling meets all regulatory requirements and is acceptable for reporting purposes. If regulators are unfamiliar with Passive Sampling, EON Products can assist in technical discussions.

Environmental Impact: Consider the reduced environmental footprint of passive sampling, as it requires less contaminated water withdrawal and disposal, no gasoline, batteries, air compressors or generators, and significantly less material waste for disposal.

Conclusion

Integrating passive groundwater sampling into your monitoring program can offer significant cost, efficiency, and environmental benefits. By understanding the strengths of both passive and traditional sampling methods, and adding passive sampling to your tool kit, you can develop a flexible, robust, and comprehensive groundwater monitoring strategy with added benefits for you and your clients.

Frequently Asked Questions

Q1: How can project managers effectively communicate the advantages of passive sampling to stakeholders who are accustomed to traditional methods?

To effectively communicate the benefits of passive groundwater sampling to stakeholders familiar with traditional methods, project managers can focus on tangible benefits and real-world examples. Begin by highlighting the cost-effectiveness of passive sampling, emphasizing savings in labor, equipment, and operational expenses. Demonstrate how these savings can be redirected to other project aspects such as remediation, enhancing overall efficiency and scope.

Next, showcase the accuracy and reliability of data obtained through passive sampling. Explain how the minimal disturbance to the water column allows samples to be acquired without disturbing the stagnant water, which eliminates labor-intensive and time-consuming purging. Clients with remote or high-traffic areas will benefit from the quick, “in-and-out” sampling enabled by passive methods. Case studies or comparisons from similar projects can show where passive sampling was proposed, tested, and used for similar applications.

Address environmental concerns by discussing the reduced environmental footprint of passive sampling. This includes less water withdrawal, lower energy consumption, and less waste, which are increasingly important in a world focused on sustainable practices.

Finally, ensure clear communication through visuals, such as graphs or charts, to compare the efficiency, cost, and accuracy of passive sampling against traditional methods. Personalize the message to the specific concerns and interests of the stakeholders, showing a direct link between passive sampling benefits and the project’s goals.

Passive Groundwater Sampling vs. Traditional Methods

Environmental consulting often involves the crucial work of managing groundwater monitoring programs at impacted sites. Assessing groundwater quality and implementing a sampling plan have traditionally involved labor-intensive sampling methods, such as purging monitoring wells, before a sample can be acquired.

Passive groundwater sampling methods, with their distinct equipment, methodology, and staffing requirements are rapidly rising as efficient alternatives.

This article will contrast passive sampling with other groundwater sampling methods, providing environmental consultants with a clear understanding of its unique attributes and benefits.

Understanding the Fundamentals of Groundwater Sampling Methods

Before diving into the specifics of passive sampling, it’s important to review the traditional groundwater sampling methods. Typically, these involve purging three to five well volumes of water or purging at a low flow rate until water quality parameters are stable. These purge techniques are in place to ensure that the sample taken is representative of the aquifer water and not biased by stagnant water pulled into the well.

Equipment Differences: The Passive Advantage

Passive sampling equipment is characterized by its simplicity and specificity.

Passive Samplers are typically small, simple, and lightweight devices that are attached to a suspension tether and lowered into monitoring wells at the desired interval of sampling.

Unlike other methods, passive sampling doesn’t require pumps or power sources, thus reducing equipment needs and potential sources of additional environmental impact.

Methodology Differences: Efficiency in Practice

The methodology of passive sampling sets it apart through its non-intrusive nature.

  • No Purging: Passive samplers bypass the stagnant zone and capture their sample directly within the well screen. Groundwater flow naturally refreshes the sample interval through the well screen, creating representative sample conditions without the need to purge the well. The samplers collect the representative water in the screen without creating water movement that could pull in stagnant water.
  • Reduced Time on Site: Since there’s no need for equipment setup or purging, the time spent on site is significantly reduced with passive sampling.

ProcessDifferences: Efficient Operations

With passive sampling, your team can spend less time monitoring each site and more time on remediation, compliance, and managing more projects.

  • Less Labor-Intensive: No setup time or purging means each sample can be collected in ten minutes or less with as little as one person on site.
  • Specialized Skills: It is easy to train staff members on the simple process of deploying and retrieving passive samplers, and they don’t need to manage complex pumping equipment.

Comparison with Low-Flow Sampling

Low-flow sampling is currently the most prevalent sampling method. It involves slowly pumping water from the well while measuring water quality parameters.  Only when the parameters stabilize can a representative sample be taken. In contrast, passive sampling:

  • Eliminates Flow Rate Concerns: There’s no need to spend time and resources to pump and monitor the flow rate and water quality with passive samplers.  This eliminates a critical, and time-consuming component of low-flow sampling.
  • Reduces Equipment Impact: Because passive sampling captures a representative sample without inducing flow, there is a lower probability that equipment will increase turbidity above site background levels when compared to active sampling methods. Artificially high turbidity can bias sample results for many contaminants, including metals and PFAS.

Analyzing Bailers: A Traditional Staple

Bailers have been a staple in groundwater sampling for their simplicity and portability. However, passive sampling offers several advantages.

  • Sample Integrity: Bailers can agitate the water column, increasing turbidity and potentially moving stagnant water from the casing through the screen, into the aquifer, affecting sample integrity. Passive samplers maintain the integrity of the groundwater while still capturing a representative sample because the only movement is natural groundwater flow through the saturated screen.
  • No Investigative Derived Waste: Passive samplers require no purging so you can eliminate the manual labor and gallons of IDW created from purging the monitoring wells.

Conclusion

Passive groundwater sampling presents a significant shift from traditional methods, offering a more efficient, cost-effective, and environmentally sensitive approach.

For environmental consultants exploring the potential of passive sampling, understanding these differences is crucial in adopting this innovative method.

Passive sampling redefines groundwater monitoring by offering a sustainable alternative that aligns with evolving needs. Are you ready to transition to a more efficient monitoring method that promises precision, ease of use, and cost-efficiency?

Book a free consultation to learn more.

Frequently Asked Questions

Q1: What site-specific factors should I consider when choosing between passive sampling and traditional methods?

When choosing between passive and traditional sampling methods, consider:

  • How long are your monitoring well screens, and at what point are they saturated with water?
  • What are the contaminants of concern that you are sampling for, and what is the minimum required volume the lab will need to test the samples.
  • The objectives of the monitoring program (e.g., compliance monitoring, site assessment).
  • Site accessibility, equipment needs, and safety concerns that may affect sampling logistics and frequency.

Q2: How can the data from passive sampling be integrated with historical data collected through other methods?

Passive sampling data can be integrated with historical data by:

  • Using side-by-side sampling to establish a correlation between passive and active methods.
  • Adjusting historical data for comparability if prior methodologies introduce biases.
  • Presenting both data sets in context that aligns with the goals of your monitoring program.

Elevating Efficiency: The Compelling Advantages of Passive Groundwater Sampling

As groundwater sampling requirements have expanded, the use of efficient, cost-effective, and environmentally friendly sampling techniques have become a more common solution. Passive sampling offers numerous advantages over traditional active sampling techniques that rely on pumping and/or purging.

This article explores the many benefits of passive sampling for those familiar with conventional groundwater sampling but new to this simpler approach.

Cost Efficiency of Passive Groundwater Sampling: Maximizing Budgets

One of the most immediate benefits of passive sampling is its impact on project budgets.

By eliminating the need for expensive pumps and the associated maintenance, consultants can see a decrease in equipment purchase and maintenance costs. More significantly, the reduction of time on-site decreases the labor cost within a groundwater monitoring program.

Industry studies corroborate these findings, with reports indicating that passive sampling can reduce sampling costs by 50-70% compared to traditional methods (source: Former McClellan AFB Study)

Smart Spending with Long-term Gains

Once passive sampling is implemented, the labor reduction can be applied again and again across multiple monitoring events, offering long-term savings. This reduction in labor cost, coupled with the minimal initial setup cost and reduced equipment needs, makes passive sampling a financially savvy choice.

Time Savings: Accelerating Project Timelines

Traditional sampling methods involve purging 3-5 well volumes or pumping until the water quality parameters stabilize.  These processes can take hours or even days on large project sites.

Passive sampling eliminates these time-consuming steps, allowing for immediate sample collection upon retrieval of the samplers. This reduction in sample time can free up consultants to spend their time on other areas, such as remediation or compliance.

Reducing Waste: A Sustainable Approach

Environmental sustainability is an added benefit of passive sampling. Passive methods do not generate purge-water waste, a common byproduct of traditional sampling methods. In the case of hazardous contaminants like PFAS, the logistics, expense, and environmental impact of waste storage and disposal are eliminated. Less hazardous waste means a cleaner and safer work environment.

Alignment with Environmental Stewardship

Passive sampling reflects the industry’s move towards more sustainable practices, aligning with the values of clients and stakeholders who prioritize environmental responsibility. Less equipment, no gasoline, batteries, or air compressors with their life-cycle impacts.

Reliable Results: Trust in Data Integrity

The integrity of sampling data is paramount, and passive sampling provides results that consultants can trust. By sampling the natural flow of groundwater as it refreshes the screened interval, accurate samples representing the aquifer can be collected without disturbing the stagnant or aerated water at other levels in the well. Over a million deployments and numerous third-party studies over the years have validated passive sampling as a reliable sampling method.

Consistency Across Sampling Events

Passive sampling methods offer consistent results over multiple sampling events. This consistency is critical for monitoring and assessing long-term trends in groundwater quality.

Industry Endorsement: The Professional Perspective

The environmental consulting industry is increasingly recognizing the benefits of passive sampling. Professional bodies and regulatory agencies endorse and use passive methods as best practices where appropriate. This professional validation is a testament to the method’s reliability and effectiveness.

Leveraging Industry Studies for Credibility

Citing industry studies and professional endorsements within environmental reports reinforces the credibility of passive sampling methodologies. For instance, studies by the Interstate Technology & Regulatory Council (ITRC) have provided guidance on the use of passive samplers, emphasizing their advantages in various monitoring scenarios.

Final Thoughts: Embracing Passive Sampling

Passive groundwater sampling offers cost efficiency, time savings, waste reduction, and reliable results that can significantly enhance the environmental monitoring and consulting landscape. For consultants ready to embrace these advantages, passive sampling is not just an option—it’s the next step towards smarter, sustainable, and scientifically robust groundwater monitoring.

Passive sampling is changing the landscape of groundwater monitoring. Are you ready to be part of this change and lead your projects with efficiency and environmental integrity?

Book a free consultation to learn more.

Frequently Asked Questions

Q1: How can the introduction of passive sampling impact the competitive positioning of an environmental consultancy?

The introduction of passive sampling can:

  • Position a consultancy as a leader in innovative, cost-effective monitoring solutions.
  • Attract clients interested in sustainable and less invasive monitoring methods.
  • Enhance the consultancy’s ability to operate in sensitive environments where traditional methods are less feasible.
  • Reduce costs and improve profit margins for groundwater monitoring projects

Q2: What are the challenges in adopting passive sampling in regions with stringent regulatory frameworks, and how can they be addressed?

Challenges include:

  • Gaining acceptance for passive methods as compliant with regulatory standards.
  • Demonstrating that passive sampling provides data of equal or superior quality to traditional methods.

Addressing these challenges can involve:

  • Engaging with regulators early in the transition process.
  • Running side-by-side tests to demonstrate the effectiveness of passive sampling
  • Contributing to or citing peer-reviewed studies that validate passive sampling methods.
  • Providing clear, transparent data and reports highlighting the reliability and relevance of passive sampling data.

What is Passive Groundwater Sampling?

Passive groundwater sampling is a technique that collects groundwater samples without the need for purging prior to sampling.

A passive sampler captures a representative sample within a specific interval of the monitoring well screen, avoiding the aerated or stagnant water at the top of the screen or in the casing. This method utilizes the natural flow of groundwater from the surrounding aquifer to refresh the monitoring well, allowing for an accurate representation of conditions.

Advantages of Passive Groundwater Sampling Over Active Sampling

Passive groundwater sampling offers several advantages over other methods:

  • Time Efficiency: Without extensive purging or waiting for stabilization, time on site is reduced.
  • Cost-Effectiveness: It saves equipment, labor, and sample disposal costs.
  • Reduced Turbidity Bias: Passive sampling will pick up any background turbidity within the well without adding any artificial, method-induced turbidity into the sample.
  • Representative Sampling: It provides samples representative of the actual groundwater conditions, free from agitation caused by pumping or bailing.
  • Environmental Considerations: Because there are few materials, no batteries, gasoline, compressed air, or electricity required, there are fewer impacts to the environment, making passive sampling a greener and more sustainable sampling solution.

Understanding the Science Behind Passive Samplers

Passive groundwater sampling uses the established principle that groundwater flowing naturally through a saturated section of well screen has the same chemical properties as the surrounding aquifer.  Passive samplers are devices that can acquire a sample of this water from the screen interval without artificially moving water from other intervals or pulling stagnant, chemically different, water in from the casing. Bypassing the stagnant water means purging and stabilization are not needed to obtain a representative sample of the aquifer.

There are two main types of passive groundwater samplers that function differently but have the same general benefits of cost reduction, ease of use, and they do not produce purge water.

  • Passive Grab Samplers, capture a whole-water sample at an interval in the saturated screen. The water and everything in the water are recovered without inducing flow in the well that could cause mixing with stagnant well water. The HydraSleeve is the most-used passive grab sampler. See Video Here.
  • Passive Diffusion Samplers collect a water sample containing contaminant molecules that have diffused through the pores of a semipermeable membrane filled with deionized water. The contaminant concentration in the sampler reaches and maintains the same concentration as the surrounding water.

Implementation of Passive Sampling in the Field

The process of implementing a passive sampling routine involves a few key steps:

  • Understand your Monitoring Well Configuration: Be sure the passive is located within the saturated screen. In wells with saturated screens longer than ten feet, consider which interval best represents the project sampling objectives, or whether multiple intervals should be sampled.  
  • Sampler Selection: Choose the correct type of passive sampler based on the contaminants of concern and the project’s objectives.
  • Deployment: Construct or purchase a simple suspension tether, attach the passive sampler(s) and lower the samplers to the intended depth.
  • Retrieval and Analysis: Retrieve the samplers any time after the minimum designated period, discharge the contents into standard laboratory bottles, and send the samples to your laboratory the same way as pumped samples. Then, simply place a new sampler on the tether and lower into the well for the next event.

Best Practices for Passive Groundwater Sampler Deployment

To ensure the accuracy and reliability of the data collected, follow standard groundwater sampling best practices, including,

  • Avoid cross-contamination: Use clean equipment and gloves during deployment, retrieval, and discharge.
  • Proper Documentation: Recording each sampler’s depth, date, and deployment and recovery time. Note and unusual occurrences and water level changes from previous events.
  • Quality Control: Acquire field equipment rinsate, and deionized water  blanks and duplicates in accordance with project requirements as quality checks on the sampling process.

EON provides several Passive Sampler SOPs to help companies help ensure they get consistent, reliable results from passive samplers.

Case Studies: Success Stories of Passive Sampling

For over 25 years, numerous case studies have demonstrated the benefits that passive groundwater sampling can bring while also providing consistent, reliable data.

For instance, at a Superfund site in California, passive sampling was shown to cost 70-80% less than per well than pumped samples. Another study at landfills in Kansas demonstrates extremely reliable data with a significantly lower cost of operation.

Passive groundwater samplers are in use across all types of groundwater monitoring sites including those managed by the USEPA, USACE, USGS, and DoD, as well as many state and private sites in the US and other countries.

Read the case studies.

Concluding Thoughts

Passive groundwater sampling represents a leap forward for groundwater monitoring. For environmental consultants looking to enhance their groundwater monitoring practices, passive sampling offers a compelling, cost-effective, and environmentally conscious choice.

By integrating these insights into your practice, passive groundwater sampling can be a game-changer in environmental monitoring. Have you considered the benefits it might bring to your projects?

Frequently Asked Questions

Q1: How can passive groundwater sampling be integrated into existing monitoring networks?

Passive groundwater sampling can be integrated into existing networks by:

  • Identifying sites where; pumping or waiting for parameters to stabilize adds to labor cost, large numbers of wells mean days at a site, high-traffic, remote locations, or equipment needs cause logistical problems, contaminated purge waste (IDW) disposal is difficult or expensive.
  • Selecting appropriate sites where sampling laboratory sample volume requirements align with passive sampler specifications.
  • Evaluating passive samplers along with traditional methods on a few representative wells at your site to compare and validate data sets.
  • Gradually transitioning monitoring wells to passive samplers, starting with those used for long-term monitoring where minimal disturbance is preferred.

Q2: What are the limitations of passive groundwater sampling and how can they be mitigated?

The limitations of passive sampling include:

  • High sampling volume requirements – if more volume is needed than is present within the saturated well screen, passive sampling may not work for your site.
  • Always reach out to your lab prior to your first passive sampling event to let them know you are transitioning methods and ask them the minimum volume required for each test. Some labs may eliminate duplicates and decrease your sampling volume required to align with your passive method.

Q3: Can passive groundwater sampling methods be used for all types of contaminants, or are there specific scenarios where they are most effective?

While passive sampling can be used to sample any contaminant found within the monitoring well, it is important to select the correct sampler for your project:

  • Passive Grab Samplers like the HydraSleeve can sample for any compound
  • If sampling for PFAS, EON recommends using an HDPE sampler
  • Passive Diffusion Samplers can be made from different membranes to sample different compounds
  • The original, Equilibrator PDB samples for VOCs only
    • The Dual Membrane PDB can sample for all dissolved compounds, including PFAS